近距离煤层回采巷道支护技术研究

153301工作面受上部3煤和9煤采空区及煤柱影响,巷道围岩变形量大。采用FLAC3D软件分别模拟不同锚杆间距和数量下的巷道围岩变形量,得到锚杆最优支护参数。针对153301工作面巷道采用锚网索和二次注浆加固支护技术,分别设计了不同的支护参数,并对支护后围岩变形量进行监测,监测结果表明围岩变形量和变形速率都有了明显的减小,支护取得了良好的效果。     

New titanium (III) phosphite structure and its application as anode for lithium ion batteries

A new titanium (III) phosphite Ti₂(HPO₃)₃, has been synthesized under hydrothermal conditions. The solid-state structure of this material was solved using single-crystal X-ray diffraction. The anionic inorganic skeleton has a three-dimensional structure, which is built up by TiO₆ octahedral units linked together via bridging HPO₃ pseudo pyramids, giving rise to tunnels along the three crystallographic axes. This new compound displays a high thermal stability limit of 625 °C. IR and Raman spectroscopies show the vibrational modes of the (HPO₃)²⁻oxoanions. Electrochemical activity of this phase toward reversible insertion of Li ion was studied for the first time by galvanostatic charge-discharge measurements, an insertion host for reversible accommodation of Li⁺ was observed.     

甲烷干重整及金属-载体相互作用

CO2和CH4均是温室气体的重要成员并且数量可观，其资源化利用对于应对气候变化和能源危机具有重要意义。甲烷干重整是经典转化方式之一，将CO2 “供氧”还原反应和CH4 “需氧”氧化反应结合起来并相互转化，其产物合成气(H2和CO)可用于费 托合成碳氢化合物液态燃料。近年来，干重整已经成为能源环境领域热点之一，在重整新工艺和催化剂设计策略方面取得了重要进展，推动了高活性和高稳定性催化剂和新工艺研发。详细综述了甲烷干重整工艺和催化剂的研究成果，重点介绍了干重整工艺新发展和催化剂功能设计，结合Ni载体相互作用、双金属协同效应、界面效应、单原子催化等新策略对干重整工艺中的基础科学问题进行了探讨，并对干重整技术现有难点和未来发展方向进行了展望。     

Fatigue damage study of cold metal transition fusion-brazed aluminium/steel dissimilar joints

ABSTRACT

An aluminium/steel CMT-welded joint is mainly composed of fusion zone (FZ), interfacial intermetallic compound (IMC) zone, and heat-affected zone (HAZ). IMC and FZ are the weakest link in the welded joint. The fatigue fracture indicates that the lattice distortion caused by the lattice mismatch of Fe₂Al₅ and Fe is more likely to engender dislocation slipping and cracks easily nucleate during the fatigue testing. The hysteresis loop is shifted to the right, which indicating that the specimen experiences a ratcheting effect. In the high-stress condition, the cyclic hardening induced by the ratcheting strain is much stronger than that in the lower stress condition, which improves the fatigue life of the materials.     

Effect of temperature on the performance of laterally constrained dielectric elastomer actuators with failure modes

This article analytically investigates the temperature influence on the performance of laterally constrained dielectric elastomer actuators. The effects of both temperature and stretches on the permittivity are taken into consideration. The governing equations of state are established by modeling the actuator as a thermodynamic system of three degrees of freedom. Various failure modes, including electromechanical instability, electric breakdown, loss of tension, and tensile rupture are considered to restrict the operation state and to determine the region of allowable state. Numerical calculations are performed to depict the variations of some important physical quantities with generalized coordinates and to gain insight on the influence of temperature on the critical curves of failures. It is shown that the temperature has obvious effects on the operation state and the allowable region. The present results can be used for designing and optimizing an actuator, and the present approach can be extended to other kinds of dielectric elastomer actuators with complex geometries.     

Unsteady conjugate mass transfer of a 2D deformable droplet in a modest extensional flow in across-slot

This work aims to investigate the unsteady conjugate interphase mass transfer between a stationary deformed drop and the modest extensional flow in a cross-intersected 2D channel. It is very difficult to accurately quantify the transient mass transfer rate of solute in such a geometry. Therefore, we established a mathematical model on the basic of the Stokes equation and solved it by the boundary element method, which could deal precisely with a two-phase flow system with a deformable interface; meanwhile, the convection-diffusion equation was solved by the finite difference method to calculate the unsteady conjugate interphase mass transfer. The simulation results showed that the mass transfer rate, analyzed and characterized in terms of mean concentration variation and Sherwood number Sh, was affected by capillary number Ca, Peclet number Pe, viscosity ratio λ , interior-to-exterior diffusivity ratio K, distribution coefficient m, and wall effect factor W.     

Co3xCu3-3x(PO4)2 microspheres,a novel non-precious metal catalyst with superior catalytic activity in hydrolysis of ammonia borane for hydrogen production

Development of robust and cheap catalyst for fast hydrogen evolution from ammonia borane (AB) aqueous solution is an interesting and important topic in the field of hydrogen energy. Herein, a novel non-precious Co_3xCu_3-3x(PO₄)₂ catalyst possessing high reactivity in AB hydrolysis has been developed for the first time. By tuning the molar ratio of Co and Cu, a series of Co_3xCu_3-3x(PO₄)₂ with different x were synthesized and the catalytic behavior in AB hydrolysis was examined. At the optimal x of 0.8, an ultrahigh turnover frequency of 72.6 min⁻¹ was achieved. Additionally, the synergistic effect between Cu₃(PO₄)₂ and Co₃(PO₄)₂ was experimentally confirmed, and the reaction kinetics of AB hydrolysis catalyzed by Co_2.4Cu_0.6(PO₄)₂ were investigated. This work provides a simple route and some new insights for the fabrication of a cheap P-containing catalyst with robust catalytic performance.     

异质性环境规制对绿色全要素生产率的影响机制——基于能源消费结构的调节作用

为探讨能源消费结构调节下异质性环境规制对绿色全要素生产率的影响机制，论文利用SBM方向距离函数测得全国各省市“经济-资源-环境-社会”四位一体的绿色全要素生产率，并将环境规制工具分为命令控制型、经济激励型、治理投入型和公众参与型4类，构建了空间杜宾模型以及门槛效应模型，进而得出在能源消费结构调节下，异质性环境规制对绿色全要素生产率的直接作用、间接作用以及空间溢出效应。研究结果表明：1）经济激励型和公众参与型环境规制通过调节能源消费结构对当地和邻地的绿色全要素生产率产生影响；2）在门槛检验方面，能源消费结构对命令控制型、经济激励型和公众参与型环境规制影响绿色全要素生产率存在门槛效应，同时在能源消费结构调节下，命令控制型和经济激励型环境规制对其本身对绿色全要素生产率的间接作用存在门槛效应。建议政府在制定环境规制时要考虑到其与能源消费结构的交互作用，并且在不同能源消费水平地区采用适宜的规制方法和强度，以更好地发挥环境规制作用。